Troubleshooting Braking Issue
If I am right about this, you should have the same problem if you apply the brakes hard while standing still. In that case, while the car isn't moving, clamp the vacuum line off with a vise grip and see if the engine still wants to stall upon brake application.
There is a one way valve in the vacuum line. The valve could be defective but you may not be able to obtain this without buying the entire booster and /or master cylinder. At 100,00 miles I suggest buying the whole unit.
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